Chemical energy


Content – Forms of energy


Chemical energy is energy stored in substances by the bindings between atoms and molecules that will be released and or used during a chemical reaction or process, in many cases this would be during combustion.

During the reaction or process the original substance undergoes a transformation to new or changed substances (products). During the reaction when the bindings between the atoms or molecules within the substance are broken, energy is used, while during the formation of the new substance (the product) energy is released.

Provided the energy needed to brake the atom bindings in the original substance is less than the energy released during formation of the new substance the new substance(s) will have less inherent chemical energy than the original substance(s).

In a closed loop, where mass cannot be exchanged with the surroundings there are three significant forms of energy; inherent energy, heat and work. The sum of energy would be constant provided the pressure and temperature within the loop remains constant. Heat would be exchanged with or transferred to the surroundings due to temperature differences.

Some examples of common substances with considerable chemical energy are: Food, petroleum, natural gas, coal, hydrogen and wood.

In an internal combustion engine the chemical energy of the gasoline and the air (oxygen) reacts (combust) and transforms into basically CO2 and H2O (if complete combustion) . The surplus energy from the transformation materialise as heat causing increased pressure (due to restricted volume) and finally work, the piston being forced outwards. During such a process some of the energy will also escape as waste heat through the cooling media and exhaust as well as mechanical work due to friction within the machinery.

The chemical energy of some substances:

Calorific Value – Energy
(Lower calorific value)
Mass     KJ/Kg Volume KJ/nm3
(at 200 C)
Hydrogen 121000  10878
Propane 46300  93164
Gasoline 44400  3,286* 107
(32856 KJ/litre)
Diesel fuel 43400  3,776* 107
(37758 KJ/litre)
Ethanol (alcohol) 26900  2,125* 107
(21251 KJ/litre)
Methanol 20000 1,580* 107
(15800 KJ/Litre)
Fat 38000  –
Protein 17000  –
Carbohydrate 17000  –